Test alloy-property claims against matched reference data
Normalize wire geometry, compare source uncertainty bounds, and diagnose confounded material claims.
Learning outcome: Separate resistance from resistivity and judge which composition or temperature comparisons support a material claim.
Starting recap
Resistance depends on material, length and cross-sectional area. A ratio compares target with reference; one means equal.
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Try
A thicker copper–nickel wire can have less resistance than a thin copper wire even when its material resistivity is higher.
Open the experimentPredict
At equal temperature and dimensions, predict the direction of the change from copper to 10% nickel alloy. Then predict how much larger the target area must be to reverse the wire resistance ranking.
Experiment
Capture the equal-area comparison and a thicker-wire counterexample. Contrast pure copper and 10% alloy temperature changes using the endpoint envelopes. Finish with the confounded temperature/composition pair and request the missing matched comparison.
Separate material evidence from wire geometry
Evaluated material reference values · original wire and site representations · Frozen NIST-hosted recommended resistivity values; wire dimensions are stipulated. Bounds use source uncertainty endpoints without assuming independence or a confidence level.
Reset keeps your prediction, captures and practice history.
Normalize the geometry before explaining the material
Reference: Pure Cu, 293 K. Target: Cu–1% Ni, 293 K. Nickel percentages in these labels are by mass. Both selected states are solid. The reference wire is stipulated to be 1 m long with area 1 mm²; target length is 1 m and area is 1 mm². These are calculated wires, not new experimental measurements.
Resistance R = ρL/A, where ρ is resistivity, L length and A cross-sectional area. Thus R₂/R₁ = (ρ₂/ρ₁)(L₂/L₁)/(A₂/A₁) = 1.698451 × 1 / 1 = 1.698451. Reference R = 0.01678 Ω; target R = 0.0285 Ω.
The source estimates ±0.5% for the reference and ±5% for the target. Using opposite endpoints gives resistivity ratio [1.605501, 1.792335] and resistance ratio [1.605501, 1.792335]. Geometry is treated as exact in this calculation. These are conservative endpoint envelopes, not independent Gaussian errors or 95% intervals.
At matched temperature and geometry, the reference resistivity increases. Both remain metals; a larger resistivity does not establish ionic bonding. A higher material resistivity can coexist with a lower wire resistance if the target is sufficiently thick. Changing area does not change the reference material value.
Before changing the area, write a prediction. Find a thickness that reverses the resistance ranking for the 10% alloy. Then compare the two temperature cases: is a change in the central value enough to establish a resolved difference under these bounds?
| Material / T | Ni mass % / atom % | ρ / 10⁻⁸ Ω m | Source estimated uncertainty |
|---|---|---|---|
| Pure Cu, 293 K | 0 / 0 | 1.678 | ±0.5% |
| Cu–0.5% Ni, 293 K | 0.5 / 0.54 | 2.23 | ±5% |
| Cu–1% Ni, 293 K | 1 / 1.08 | 2.85 | ±5% |
| Cu–3% Ni, 293 K | 3 / 3.24 | 5.32 | ±5% |
| Cu–5% Ni, 293 K | 5 / 5.39 | 7.77 | ±5% |
| Cu–10% Ni, 293 K | 10 / 10.73 | 13.89 | ±5% |
| Pure Cu, 400 K | 0 / 0 | 2.398 | ±1% |
| Cu–10% Ni, 400 K | 10 / 10.73 | 14.81 | ±3% |
Source definitions and comparison limits
Ho et al. (1983), Electrical Resistivity of Ten Selected Binary Alloy Systems, Table 4, printed p. 228. Accessed 2026-10-28. Recommended, smoothed reference values for well-homogenized alloys with low clustering, without severe quenching or cold work. Pure copper is well-annealed and high-purity. Room-temperature dimensions are used without thermal-expansion correction (printed pp. 187–188, 227, 240). Exact impurity concentrations, pressure, common specimen preparation and covariance are not specified for these recommended rows. The stated percentages are source estimated uncertainties, not declared confidence intervals. All selected rows are unstarred; source stars elsewhere flag temperature ranges without experimental data. These values are evaluated recommendations, not a new raw-data cohort. Only selected factual numbers are reproduced; diagrams and tasks are original.
Target/reference resistance = 1.698451.
At matched temperature and geometry, the reference resistivity increases. Both remain metals; a larger resistivity does not establish ionic bonding.
Captures retain your reference comparison and wire geometry or each editable substitution site. Replay recalculates the source comparison and your counting representation; it does not measure a new alloy, infer a unique structure or grade the explanation.
Understand
Apply
Public practice checks a specific claim. It does not establish independent mastery.
Write a supported claim, a competing geometry or preparation explanation, and an observation that would distinguish them. Explain why higher resistivity does not turn a metal into an ionic solid.
Continue
Completion requires a saved prediction, at least one capture and a reflection. Presence checks do not grade your reasoning.
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