Build a fixed-number partition sum with exclusion
Consider two identical spin-polarized noninteracting fermions and four nondegenerate one-particle states of energies 0,delta,2delta,3delta. Spin polarization means each listed state has capacity one. At fixed N=2, allowed configurations are unordered pairs of distinct indices: (0,1),(0,2),(0,3),(1,2),(1,3),(2,3). There are six, not sixteen.
Learning outcome: List all six configurations and normalize their weights for two temperature ratios. Reconstruct each level occupancy and total energy, then repeat with sixteen distinguishable configurations. Explain why a one-level occupancy greater than one would reject the spin-polarized fermion description.
Starting recap
Review finite sums, exponential and logarithmic functions, radial integration measures, first-order coupled equations and mass-energy units. Keep state counts, occupations, calibration records and unused tests distinct.
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In a changed analytic packet set q=exp[−delta/(kBT)]=1/2. Pair weights sum to q+q²+2q³+q^4+q^5=35/32. Fermion ground-level occupancy is (q+q²+q³)/Z=4/5. The distinguishable comparison gives 2/(1+q+q²+q³)=16/15, illustrating the exclusion difference.
Open the experimentPredict
What is fixed in both of these canonical comparisons?
Experiment
List all six configurations and normalize their weights for two temperature ratios. Reconstruct each level occupancy and total energy, then repeat with sixteen distinguishable configurations. Explain why a one-level occupancy greater than one would reject the spin-polarized fermion description.
Keep fixed particle number while changing counting rules
Worked teaching model · synthetic values · Two identical spin-polarized noninteracting fermions occupy four nondegenerate one-particle states with energies 0, delta, 2delta, 3delta, canonical equilibrium at fixed N=2. Compare two distinguishable noninteracting classical particles in the same finite states, where repeated occupancy is allowed. This is not a grand-canonical approximation or a real-material equation of state.
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Same levels and temperature, different allowed configurations
Graph axes rescale independently; read units and values, not screen angles. 1: canonical spin-polarized fermions (solid).2: two distinguishable classical particles (dashed). Joined curves show the supplied model, not additional observations.
Equivalent numerical coordinates for Same levels and temperature, different allowed configurations
canonical spin-polarized fermions
| one-particle energy (eV) | mean occupancy |
|---|---|
| 0 | 0.8807971 |
| 1 | 0.6944133 |
| 2 | 0.3055867 |
| 3 | 0.1192029 |
At most 82 representative computed coordinates including endpoints; the plotted curve can use a finer grid. A table of a revealed generator is not independent measurement evidence.
two distinguishable classical particles
| one-particle energy (eV) | mean occupancy |
|---|---|
| 0 | 1.287829 |
| 1 | 0.4737656 |
| 2 | 0.1742886 |
| 3 | 0.06411721 |
At most 82 representative computed coordinates including endpoints; the plotted curve can use a finer grid. A table of a revealed generator is not independent measurement evidence.
| Quantity | Value | Unit |
|---|---|---|
| Canonical fermion configurations | 6 | integer |
| Distinguishable classical ordered configurations | 16 | integer |
| Fermion mean total energy | 1.663195 | eV |
| Classical mean total energy | 1.014695 | eV |
| Fermion ground-state occupancy | 0.8807971 | particles |
| Classical ground-state mean occupancy | 1.287829 | particles |
| Fermion total mean particle count | 2 | particles |
Exclusion changes the allowed configurations before the thermal weights are normalized.
Enumerate six unordered distinct-level pairs i<j with Boltzmann weight exp[−(Ei+Ej)/kBT]. Normalize the pair partition function, then sum pair probabilities containing each level. For the distinguishable comparison there are 16 ordered pairs, including repetition, and mean occupancy2exp(−Ei/kBT)/z1. Both have exactly two particles; a chemical-potential Fermi function is not substituted for this small fixed-N canonical enumeration.
Predict before inspecting the values. Save contrasting records with assumptions and one alternative explanation. This virtual display does not certify practical measurement technique.
Exclusion changes the allowed configurations before the thermal weights are normalized.
Enumerate six unordered distinct-level pairs i<j with Boltzmann weight exp[−(Ei+Ej)/kBT]. Normalize the pair partition function, then sum pair probabilities containing each level. For the distinguishable comparison there are 16 ordered pairs, including repetition, and mean occupancy2exp(−Ei/kBT)/z1. Both have exactly two particles; a chemical-potential Fermi function is not substituted for this small fixed-N canonical enumeration.
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