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SCIENCE · INVESTIGATE AND EXPLAIN

Turn an occupation probability into a count using the state measure

The Fermi occupation probability for one state is f(E)=1/[1+exp((E−mu)/(kBT))]. It lies between zero and one and equals one half at E=mu. Occupation probability alone is not a particle count. To count occupied states in an energy interval, multiply by the density of states D(E) and integrate over energy.

Learning outcome: Derive the analytic count integral and check it against numerical integration. Compare 160 and 320 panels for energy, labeling the difference honestly. Change mu and theta separately and distinguish a chemical-potential-controlled calculation from a fixed-particle-number problem.

Starting recap

Review finite sums, exponential and logarithmic functions, radial integration measures, first-order coupled equations and mass-energy units. Keep state counts, occupations, calibration records and unused tests distinct.

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Try

At mu=2 eV and theta=0.5 eV, the eight-state band is half occupied: N=4 exactly by symmetry. Occupation at E=mu is 0.5, whereas occupied state density there is 1 state/eV. Integrating only f would miss the supplied DOS factor and yield the wrong count units.

Open the experiment

Predict

Which integral gives the particle count in the supplied band?

Experiment

Derive the analytic count integral and check it against numerical integration. Compare 160 and 320 panels for energy, labeling the difference honestly. Change mu and theta separately and distinguish a chemical-potential-controlled calculation from a fixed-particle-number problem.

Integrate occupied states, not occupation alone

Worked teaching model · synthetic values · Supplied finite band from 0 to 4 eV with constant DOS2 states/eV, including spin. Occupation f=1/[1+exp((E−mu)/kBT)]. Chemical potential is a control, so particle number need not stay fixed. This constant finite DOS is not the three-dimensional free-electron square-root DOS. Simpson resolution comparison is a diagnostic, not a rigorous error bound.

Reset keeps your prediction, captures and practice history.

Occupation probability and a finite density of states

occupied states per eVenergy (eV)041.9640280

Graph axes rescale independently; read units and values, not screen angles. 1: DOS times occupation (solid). Joined curves show the supplied model, not additional observations.

Equivalent numerical coordinates for Occupation probability and a finite density of states

DOS times occupation

energy (eV)occupied states per eV
01.964028
0.066666671.959002
0.13333331.953291
0.21.946806
0.26666671.939449
0.33333331.93111
0.41.921669
0.46666671.910993
0.53333331.89894
0.61.885352
0.66666671.870062
0.73333331.852892
0.81.833655
0.86666671.812157
0.93333331.788202
11.761594
1.0666671.732144
1.1333331.699677
1.21.664037
1.2666671.6251
1.3333331.582783
1.41.53705
1.4666671.487925
1.5333331.435502
1.61.379949
1.6666671.321513
1.7333331.26052
1.81.197375
1.8666671.132549
1.9333331.066568
21
2.0666670.9334319
2.1333330.8674512
2.20.8026247
2.2666670.7394796
2.3333330.6784873
2.40.620051
2.4666670.5644979
2.5333330.512075
2.60.4629504
2.6666670.4172171
2.7333330.3748996
2.80.3359632
2.8666670.3003234
2.9333330.2678558
30.2384058
3.0666670.2117979
3.1333330.187843
3.20.1663454
3.2666670.1471084
3.3333330.1299383
3.40.1146484
3.4666670.1010603
3.5333330.08900671
3.60.07833145
3.6666670.06889039
3.7333330.06055138
3.80.05319399
3.8666670.04670903
3.9333330.04099802
40.03597242

At most 82 representative computed coordinates including endpoints; the plotted curve can use a finer grid. A table of a revealed generator is not independent measurement evidence.

Calculated quantities under the declared measurement model
QuantityValueUnit
Occupation at chemical potential0.5ratio
Occupied particle count in finite band4particles
Available states in finite band8states
Energy integral with 160 panels4.731635eV
Energy integral with 320 panels4.731635eV
Signed resolution difference3.935972e-10eV
Unoccupied state count4states

Integrate density of states times occupation to obtain count; changing chemical potential is not a fixed-particle-number experiment.

For constant DOS D, integrate f analytically: N=D kBT{ln[1+exp(mu/kBT)]−ln[1+exp((mu−W)/kBT)]}, W=4 eV. The energy integral includes an extra E and is evaluated at two Simpson resolutions. Their difference is a numerical diagnostic, not a guaranteed error bound. At mu=W/2, f(E)+f(W−E)=1 and N=DW/2=4 exactly by symmetry.

Predict before inspecting the values. Save contrasting records with assumptions and one alternative explanation. This virtual display does not certify practical measurement technique.

Integrate density of states times occupation to obtain count; changing chemical potential is not a fixed-particle-number experiment.

For constant DOS D, integrate f analytically: N=D kBT{ln[1+exp(mu/kBT)]−ln[1+exp((mu−W)/kBT)]}, W=4 eV. The energy integral includes an extra E and is evaluated at two Simpson resolutions. Their difference is a numerical diagnostic, not a guaranteed error bound. At mu=W/2, f(E)+f(W−E)=1 and N=DW/2=4 exactly by symmetry.

Captures preserve recipes and replay their calculated results. They are synthetic model evidence, not physical measurements.

Understand

Define the state and evidence

The Fermi occupation probability for one state is f(E)=1/[1+exp((E−mu)/(kBT))]. It lies between zero and one and equals one half at E=mu. Occupation probability alone is not a particle count. To count occupied states in an energy interval, multiply by the density of states D(E) and integrate over energy.

Derive the quantitative relation

This original bounded packet supplies a constant DOS of 2 states/eV on a finite band from 0 to 4 eV, including spin. Thus only eight states are available in the continuous DOS approximation. It is deliberately not the square-root DOS of a three-dimensional free-electron metal. With theta=kBT, integration gives N=2theta times (ln[1+exp(mu/theta)]−ln[1+exp((mu−4)/theta)]).

Test a changed model or boundary

Energy needs an additional factor E: U=integral0to4 2E f(E)dE. The workbench evaluates this integral with composite Simpson weights 1,4,2,…,4,1 at 160 and 320 panels and reports their signed difference. A resolution difference is a convergence diagnostic, not a rigorous error bound. A theorem-based bound would require a suitable fourth-derivative bound over the full interval.

Limit the inference

Chemical potential is independently controlled here, so changing temperature can change particle number. A fixed-density material problem would instead solve the count equation for mu at each temperature. At the special symmetric setting mu=2 eV, f(E)+f(4−E)=1, so N=4 at every positive temperature in this finite-band model. This symmetry does not make the total energy temperature independent.

Worked original case

At mu=2 eV and theta=0.5 eV, the eight-state band is half occupied: N=4 exactly by symmetry. Occupation at E=mu is 0.5, whereas occupied state density there is 1 state/eV. Integrating only f would miss the supplied DOS factor and yield the wrong count units.

Investigation

Derive the analytic count integral and check it against numerical integration. Compare 160 and 320 panels for energy, labeling the difference honestly. Change mu and theta separately and distinguish a chemical-potential-controlled calculation from a fixed-particle-number problem.

Changed-case practice

Try the changed case before feedback

For the same constant DOS2 states/eV but symmetric band0 to6 eV and mu=3 eV, find N at positive temperature.

This practice is public and unsaved. A matching number does not verify understanding. Retain your explanation, assumptions and changed-case evidence in the separate course workspace.

Sources and boundaries

Original derivations and virtual evidence checked 31 October 2026 against the primary explanation. All questions and numerical packets are original. Supplied theoretical distributions and synthetic records are not actual laboratory measurements. No nuclear, electrical, heating, beam or material-handling procedures are requested. Retain first reasoning, actual criterion critique, revision and a separately assigned unfamiliar task in the course evidence workspace; public keys do not authenticate mastery.

The numerical quadrature rule is independently sourced to OpenStax Calculus II, numerical integration.

Apply

Which integral gives the particle count in the supplied band?

Public practice checks a specific claim. It does not establish independent mastery.

Which independent calibration, state-counting or physical-domain premise is needed, and which fresh observation could challenge the inference?

Continue

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