Audit a complete electrical-to-thermal process across changing boundaries
A correct equation can still answer the wrong system question. An ideal constant-potential source charges an initially empty capacitor through resistance, then is disconnected. The charged capacitor later discharges into a thermal arrangement that transfers only a stated fraction of energy to a gas. The gas may expand or remain at fixed volume. Treat these as separate stages with separate boundaries before adding their ledgers.
Learning outcome: Retain both gas constraints at 8 V, then repeat at 12 V. Freeze each stage ledger first, check the V² scaling and compare temperature rise, pressure/volume ratios and work signs. Reconstruct the complete source account without counting an intermediate transfer twice.
Starting recap
Choose each system boundary and interval before applying an equation. Distinguish agreement from independent evidence and preserve earlier reports.
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At V=8 V and C=0.020 F, source energy is 1.28 J, storage and charging heat are each 0.64 J. Of the storage, 0.48 J heats the gas and 0.16 J goes elsewhere. Constant-pressure gas receives 0.288 J internal-energy gain and performs 0.192 J work; fixed-volume gas instead gains the full 0.48 J internally.
Open the experimentPredict
Does changing the gas constraint change the amount of energy the charging source supplied?
Experiment
Retain both gas constraints at 8 V, then repeat at 12 V. Freeze each stage ledger first, check the V² scaling and compare temperature rise, pressure/volume ratios and work signs. Reconstruct the complete source account without counting an intermediate transfer twice.
Audit source, capacitor and gas energy stages
Worked teaching model · synthetic values · Initially uncharged C=0.020 F capacitor charges fully from an ideal constant-potential source through resistance, then is disconnected and fully discharged. 75% of stored energy heats 0.001 mol ideal monatomic gas initially at 300 K; 25% escapes elsewhere. Constant-volume or quasistatic constant-pressure gas. Aggregate endpoint energy only; no physical wiring, pressure vessel or RC transient calculation.
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Cross-boundary evidence ledger
Each stage uses its own boundary; capacitor storage is not the entire charging-source energy.
No energy is counted twice: add charging heat, discharge leakage, gas internal-energy gain and gas work to recover source input. For the gas ΔU=Q+W_on=Q−W_by. Constant-pressure heating has a smaller temperature rise than fixed-volume heating for equal Q because expansion transfers energy as work. Ideal endpoint balances do not specify a time course or certify real equipment.
| Quantity | Value | Unit |
|---|---|---|
| Charge delivered by source | 0.16 | C |
| Source energy delivered during charging | 1.28 | J |
| Stored capacitor energy before discharge | 0.64 | J |
| Charging resistance thermal conversion | 0.64 | J |
| Heat delivered to gas | 0.48 | J |
| Discharge energy to other surroundings | 0.16 | J |
| Gas internal-energy increase | 0.48 | J |
| Work done by gas | 0 | J |
| Work done on gas | 0 | J |
| Gas temperature increase | 38.4872 | K |
| Final gas temperature | 338.487 | K |
| Final to initial pressure ratio | 1.12829 | ratio |
| Final to initial volume ratio | 1 | ratio |
| Complete source-energy account | 1.28 | J |
Follow each stage without adding its input twice
Charge from ideal source
1.28 J input = 0.64 J retained or passed to the named next subsystem + 0.64 J output.
Retained in capacitor; output is charging resistance thermal conversion.
Top outline: stage input. Lower solid: named retained share. Lower dashed: output share. Each stage has its own input-normalized scale.
Discharge isolated capacitor
0.64 J input = 0.48 J retained or passed to the named next subsystem + 0.16 J output.
Energy delivered as gas heat; output reaches other surroundings.
Top outline: stage input. Lower solid: named retained share. Lower dashed: output share. Each stage has its own input-normalized scale.
Gas thermal process
0.48 J input = 0.48 J retained or passed to the named next subsystem + 0 J output.
Retained gas internal energy; output is work by gas. Fixed volume gives zero work.
Top outline: stage input. Lower solid: named retained share. Lower dashed: output share. Each stage has its own input-normalized scale.
Each stage uses its own boundary; capacitor storage is not the entire charging-source energy.
No energy is counted twice: add charging heat, discharge leakage, gas internal-energy gain and gas work to recover source input. For the gas ΔU=Q+W_on=Q−W_by. Constant-pressure heating has a smaller temperature rise than fixed-volume heating for equal Q because expansion transfers energy as work. Ideal endpoint balances do not specify a time course or certify real equipment.
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Public practice checks a specific claim. It does not establish independent mastery.
Which independent observations would be needed before replacing the stipulated 75% heat fraction with an empirical efficiency?
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